| Cao Cao | Clear 3 Wei Musou Modes |
| Cao Ren | Complete target 2 Fan Castle - Lu Bu side |
| Chaos Difficulty | Complete 1 Wei, Shu, Wu, Other Musou Mode |
| Character Costumes | Raise a character to level 50 |
| Diao Chan | Complete 1 Wei, Shu, Wu Musou Mode |
| Dong Zhuo | Complete target 1 Hu Lao Gate - Lu Bu side |
| Gan Ning | Complete 1 Wu Musou Mode |
| Guan Ping | Complete target 2 Fan Castle - Shu side |
| Huang Gai | Complete target 3 Chi Bi - Wu side |
| Huang Zhong | Complete target 1 Ding Jun - Wei side |
| Liu Bei | Complete 3 Shu Musou Mode |
| Lu Bu | Complete Sun Jian, Liu Bei, Cao Cao, and Diao Chan usou mode |
| Lu Meng | Succeed in 2 battle objectives on the Wei side of He Fei |
| Ma Chao | Succeed in battle objective 2 on the Wei side of Han Zhong Attack Defense Battle |
| Pang Tong | Succeed in 3 battle objectives at Cheng Du battle and finish battle with Pang Tong alive |
| Sun Ce | Succeed in Battle Objective 1 on the Sun Jian side of the Battle of Xia Pi |
| Sun Jian | Complete 3 Wu Musou Mode |
| Sun Quan | Succeed in Battle Objective 1 on the Lu Bu side of The Battle of Chi Bi |
| Very Hard Difficulty | Clear Musou Mode with any character |
| Voice Gallery | Raise a character to level 50 |
| Wei Yan | Succeed in 2 battle objectives on the Shu side of WuZhang Plains and finish battle with Wei Yan alive |
| Xiahou Yuan | Succeed in 1 battle objective on the Shu side of Ding Jun Mountain |
| Xiao Qiao | Succeed in Battle Objective 3 on the Wu side of the Battle of Shi Ting |
| Xu Huang | Succeed in 2 battle objectives on the Wei/Wu side of Fan Castle |
| Yuan Shao | As Wei, complete all 3 targets and capture Wu Chao before completing the stage. |
| Zhang Jiao | Beat stage with completing all three targets in the Yellow Turban Rebellion. |
| Zhang Liao | Complete 1 Wei Musou Mode |
| Zhou Tai | Succeed in 3 battle objectives on the Shu side of Yi Ling |
| Zhuge Liang | Complete 1 Shu Musou Mode |
